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Thermogravimetric and Fourier Transform Infrared Analysis of Switchgrass Pyrolysis
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  • Thermogravimetric and Fourier Transform Infrared Analysis of Switchgrass Pyrolysis
  • Thermogravimetric and Fourier Transform Infrared Analysis of Switchgrass Pyrolysis
저자명
이성범,Lee. Seong-Beom,Fasina. Oladiran O.
간행물명
바이오시스템공학
권/호정보
2009년|34권 1호|pp.44-49 (6 pages)
발행정보
한국농업기계학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

This study was conducted to investigate the pyrolysis characteristics of switchgrass using TGA-FTIR instrument. Switchgrass is a high yielding perennial grass that has been designated as a potential energy crop, because of its high energy value. Ground switchgrass were pyrolysed at different heating rates of 10, 20, 30, and $40^{circ}C/min$ in a TGA-FTIR instrument. The thermal decomposition characteristics of switchgrass were analyzed, and the gases volatilized during the experiment were identified. The thermal decomposition of switchgrass started at approximately $220^{circ}C$, followed by a major loss of weight, where the main volatilization occurred, and the thermal decomposition was essentially completed by $430^{circ}C$. The pyrolysis process was found to compose of four stages; moisture evaporation, hemicellulose decomposition, cellulose decomposition, and lignin degradation. The peak temperatures for hemicellulose decomposition ($306^{circ}C$ to $327^{circ}C$) and cellulose decomposition ($351^{circ}C$ to $369^{circ}C$) were increased with greater heating rates. FTIR analysis showed that the following gases were released during the pyrolysis of switchgrass; $CO_2$, CO, $CH_4$, $NH_3$, COS, $C_{2}H_{4}$, and some acetic acid. The most gas species were released at low temperature from 310 to $380^{circ}C$, which was corresponding well with the observation of thermal decomposition.