The non-rigid molecule group theory in which the dynamical symmetry operations are defined as physical operations is applied to deduce the character table of the full non-rigid molecule group (f-NRG) of 2,3,5,6-Tetramethylpyrazine The f-NRG of this molecule is seen to be isomorphic to the group $mathbb{Z}_3{wr}(mathbb{Z}_2{ imes}mathbb{Z}_2)$, where $mathbb{Z}_n$ is the cyclic group of order n, of order 324 which has 45 conjugacy classes. We determine the some properties and relations between characters of the group. Also, we examine the symmetry group of this molecule and show that its symmetry group is $mathbb{Z}_2{ imes}mathbb{Z}_2$.