The internal flow field in a centrifugal pump working at the several flow conditions has been measured by using the particle image velocimetry (PIV) technique with the laser induced fluorescence (LIF) particles and the refractive index matched (RIM) facilities. The impeller of the centrifugal pump has an outlet diameter in 100mm, and consists of six two-dimensional curvature backward swept blades of constant thickness. Measured results give reliable flow patterns in the pump. It is obvious that application of LIF particle and RIM are the key methods to obtain the right PIV measured results in pump internal flow.