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Polymerization of Methyl Methacrylate in Carbon Dioxide Using Glycidyl Methacrylate Linked Reactive Stabilizer: Effect of Pressure, Reaction Time, and Mixing
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  • Polymerization of Methyl Methacrylate in Carbon Dioxide Using Glycidyl Methacrylate Linked Reactive Stabilizer: Effect of Pressure, Reaction Time, and Mixing
  • Polymerization of Methyl Methacrylate in Carbon Dioxide Using Glycidyl Methacrylate Linked Reactive Stabilizer: Effect of Pressure, Reaction Time, and Mixing
저자명
Han. Sang-Hun,Park. Kyung-Kyu,Lee. Sang-Ho
간행물명
Macromolecular research
권/호정보
2009년|17권 1호|pp.51-57 (7 pages)
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한국고분자학회
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정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Using glycidyl methacrylate-linked poly(dimethylsiloxane), methyl methacrylate was polymerized in supercritical $CO_2$. The effects of $CO_2$ pressure, reaction time, and mixing on the yield, molecular weight, and molecular weight distribution (MWD) of the poly(methyl methacrylate) (PMMA) products were investigated. The shape, number average particle diameter, and particle size distribution (PSD) of the PMMA were characterized. Between 69 and 483 bar, the yield and molar mass of the PMMA products showed a trend of increasing with increasing $CO_2$ pressure. However, the yield leveled off at around 345 bar and the particle diameter of the PMMA increased until the pressure reached 345 bar and decreased thereafter. With increasing pressure, MWD became more uniform while PSD was unaffected. As the reaction time was extended at 207 bar, the particle diameter of PMMA decreased at $0.48{pm}0.03%$ AIBN, but increased at 0.25% AIBN. Mixing the reactant mixture increased the PMMA yield by 18.6% and 9.3% at 138 and 207 bar, respectively.