In the fire there are fusion signs and damage by fire, and insulation aging and carbonization of the electric wiring in the ignition spot because of special characteristic of the appliance in the electricity fire. Because of the physical factor applied in the damage of fire, the decision of ignition spot by eye investigation is insufficient. In this paper, the cause of electricity fire is researched. The focus is on the operation state of operated MCCB(Molded Case Circuit Breaker) at the time of electricity fire. Through grasping the operation principle of MCCB and the experiment, the state of MCCB after fire suppression is discriminated. The distinction possibility on the exist of electricity fire is proposed.