So far, many researches have been done to retrieve music information using static classification descriptors such as genre and mood. Since static classification descriptors are based on diverse content-based musical features, they are effective in retrieving similar music in terms of such features. However, human emotion or mood transition triggered by music enables more effective and sophisticated query in music retrieval. So far, few works have been done to evaluate the effect of human mood transition by music. Using formal representation of such mood transitions, we can provide personalized service more effectively in the new applications such as music recommendation. In this paper, we first propose our Emotion State Transition Model (ESTM) for describing human mood transition by music and then describe a music classification and recommendation scheme based on the ESTM. In the experiment, diverse content-based features were extracted from music clips, dimensionally reduced by NMF (Non-negative Matrix Factorization, and classified by SVM (Support Vector Machine). In the performance analysis, we achieved average accuracy 67.54% and maximum accuracy 87.78%.