In this study, boiling heat transfer coefficients(HTCs) and critical heat flux(CHF) are measured on a smooth square flat copper heater in a pool of pure water with and without carbon nano tubes(CNTs) dispersed at $60^{circ}C$. Tested aqueous nanofluids are prepared using multi-walled CNTs whose volume concentrations are 0.0001, 0.001, 0.01, and 0.05%. For dispersion of CNTs, polyvinyl pyrrolidone(PVP) is used in distilled water. Pool boiling HTCs are taken from $10kW/m^2$ to critical heat flux for all nanofluids. Test results show that the pool boiling HTCs of the nanofluids are lower than those of pure water in entire nucleate boiling regime. On the other hand, critical heat flux is enhanced greatly showing up to 200% increase at volume concentration of 0.001% CNTs as compared to that of pure water. This is related to the change of surface characteristics by the deposition of CNTs. This deposition makes a thin CNT layer on the surface and the active nucleation sites of heat transfer surface are decreased due to this layer. The thin layer acts as the thermal resistance and also decreases the bubble generation rate resulting in a decrease in pool boiling HTCs. The same layer, however, maintains the nucleate boiling even at very high heat fluxes and reduces the formation of large vapor canopy at near CHF resulting in a significant increase in CHF.