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Effect of Bimetallic Pt-Rh and Trimetallic Pt-Pd-Rh Catalysts for Low Temperature Catalytic Combustion of Methane
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  • Effect of Bimetallic Pt-Rh and Trimetallic Pt-Pd-Rh Catalysts for Low Temperature Catalytic Combustion of Methane
  • Effect of Bimetallic Pt-Rh and Trimetallic Pt-Pd-Rh Catalysts for Low Temperature Catalytic Combustion of Methane
저자명
Bhagiyalakshmi. Margandan,Anuradha. Ramani,Park. Sang-Do,Park. Tae-Sung,Cha. Wang-Seog,Jang. Hyun-Tae
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2010년|31권 1호|pp.120-124 (5 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Monometallic, bimetallic and trimetallic particles consisting of different weight compositions of Pt-Pd-Rh over pure alumina wash coats have been synthesized and their catalytic performance on methane conversion was studied from 150 to $600^{circ}C$. Different catalyst formulations with variable Pt, Pd and Rh contents for bimetallic and trimetallic systems were tried and $Pt_{(1.5)}Rh_{(0.3)}/Al_2O_3$ and $Pt_{(1.0)}Pd_{(1.0)}Rh_{(0.3)}/Al_2O_3$ shows low $T_{50}$ and $T_{90}$ temperatures. Bimetallic and trimetallic particle synergism acts as three way catalysts and therefore, all the catalysts show 100% methane conversion. The effect of supports such as $ZrO_2$ and $TiO_2$ on methane combustion was investigated; from $T_{50}$ and $T_{90}$ results both $Al_2O_3$ and $ZrO_2$ are suitable supports for low temperature methane combustion.