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Multichannel Quantum-Defect Study of q reversals in Overlapping Resonances in Systems involving 1 Open and 2 Closed Channels
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  • Multichannel Quantum-Defect Study of q reversals in Overlapping Resonances in Systems involving 1 Open and 2 Closed Channels
  • Multichannel Quantum-Defect Study of q reversals in Overlapping Resonances in Systems involving 1 Open and 2 Closed Channels
저자명
Cho. Byung-Hoon,Lee. Chun-Woo
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2010년|31권 2호|pp.315-326 (12 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

This study examined the overlapping resonances in the systems involving 1 open and 2 closed channels using the phase-shifted version of multichannel quantum-defect theory (MQDT). The results showed that 21 patterns for the q reversals in the autoionization spectra are possible depending on the relative arrangements of the two simple poles and roots of the quadratic equations. Complete cases could be generated easily using the q zero planes determined using only 3 asymmetric spectral line profile indices. The transition of the spectra of the coarse interloper Rydberg series from the lines into a structured continuum by being dispersed onto the entire Rydberg series was found. The overall behavior of the time delays was found to be governed by the dense Rydberg series, which is quite different from the one of the autoionization cross sections that is governed by an interloper, indicating that different dynamics prevail for them. This is in contrast to the two channel system where both quantities behave similarly. The dynamics obtained in the presence of overlapping resonances is as follows. The absorption process is instant and dominated by a transition to the interloper line. This process is followed by rapid leakage into the dense Rydberg series, which has a longer residence time before ionization than that of the interloper state. This is because the orbiting period is proportional to $upsilon^3$ so that an excited electron has a shorter lifetime in the interloper state belonging to a lower member of the Rydberg series.