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Reaction Behavior of Li4+xTi5O12 Anode Material as Depth of Discharge
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  • Reaction Behavior of Li4+xTi5O12 Anode Material as Depth of Discharge
  • Reaction Behavior of Li4+xTi5O12 Anode Material as Depth of Discharge
저자명
Cho. Woo-Suk,Song. Jun-Ho,Park. Min-Sik,Kim. Jae-Hun,Kim. Jeom-Soo,Kim. Young-Jun
간행물명
Journal of electrochemical science and technology
권/호정보
2010년|1권 2호|pp.85-91 (7 pages)
발행정보
한국전기화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

We have studied the origin of an additional plateau of $Li_{4+x}Ti_5O_{12}$ (LTO) observed at 0.7 V (vs. Li/$Li^+$). Some LTO has to be discharged down to below 1.0 V forming two-stage plateau (1.5 V and 0.7 V) in order to obtain most of capacity while others could achieve the same level of capacity at higher potential (1.0 V vs. Li/$Li^+$) forming one plateau (1.5 V). The particle size effect has been investigated as a possible reason of this. The 0.7 V plateau was gradually elongated with increasing the particle size. The structural variations and kinetic behaviors during discharge were carefully examined by in-situ XRD technique and OCV measurement. According to structural and electrochemical verifications, the kinetic limitation of $Li^+$ insertion is responsible primarily for the two-stage plateau which is related to the particle size of LTO rather than the formation of new intermediate phase during discharge. Herein, we propose a possible reaction model to elucidate this abnormal behavior of LTO below 1.0 V (Li/$Li^+$).