- 니켈계 유사 하이드로탈사이트 촉매상에서 n-헥사데칸의 수증기 개질에 의한 수소 생산
- ㆍ 저자명
- 이승환,문동주,Lee. Seung-Hwan,Moon. Dong-Ju
- ㆍ 간행물명
- 한국수소 및 신에너지학회 논문집
- ㆍ 권/호정보
- 2010년|21권 5호|pp.412-418 (7 pages)
- ㆍ 발행정보
- 한국수소및신에너지학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Steam reforming of n-hexadecane, a major component of diesel over Ni-based hydrotalcite-like catalyst was carried out at $900^{circ}C$ at atmospheric pressure with space velocity of $10,000h^{-1}$ and feed molar ratio of steam/carbon=3.0. Ni-based hydrotalcite catalyst was prepared by a solid phase crystallization (spc) method and characterized by $N_2$-physisorption, CO chemisorption, TPR., XRD, and TEM techniques. It was found that spc Ni/MgAl catalyst showed higher catalytic stability and inhibition of carbon formation than Ni/$gamma-Al_2O_3$ catalyst under the tested conditions. The results suggest that the modified spc-Ni/MgAl catalyst after optimization may be applied for the SR reaction of diesel.