Thermal vibration characteristics of a thin walled composite beam attached on spacecraft are investigated in this paper. The composite beam is assumed to have a thin CUS(circumferentially uniform stiffness) wall and modeled with several composite materials which are already space qualified such as T300/Epoxy, YS90AEpoxy. Steady state angle and peak to peak error in spacecraft attitude angle and tip displacement of composite beams are evaluated as a performance index for thermal vibration characteristics. Evaluation results shows that composite beam made out of YS90A has nearly 2 times better than T300 in terms of peak to peak attitude error angle.