In this study, tank truck incidents of road transport of hazardous materials to experimental investigated the potential fire hazard. Real scale fire was to perform experiments for on this qualitative and quantitative data collection and analysis. Particularly affected by radiant heat from the flames caused and damage estimates range investigated accordingly. Flame temperature, internal temperature of tank and emitted radiation from the flames was investigated. The flame of light oil spill caused a fire at a temperature of about $300^{circ}C$ high in comparison with the methanol by combustion of diesel and methanol, according to the difference, the flame duration changes varies depending on the Burning rate, amount of radiant heat flux from light oil fire was 4 times increases compared with fire of methanol. Depending on spill locations(kinds of road surfaces, absorbing rate) and the longer the duration of the flame important factors for the internal temperature of tank truck rise was found. Dirt roads than paved road accident in a fire caused by leakage of hazardous was could the higher the damaged. Therefor, Fire suppression activities should be required in particular to be around.