This is a basic experimental study to apply FRP modular box member to a variety of construction structures exposed to flexural strength, such as a slab and a girder. Tests were conducted under various conditions in order to analyze jointing performance features of the developed FRP modular box member as a large section. For the methods of jointing FRP modular box member, chemical connection, mechanical connection, and a combination of both were used to test both vertical and horizontal jointing. As a result of the test, using urethane+two bolts+sheets was the most efficient method of connecting FRP modular box member, and confirmed the efficient behavior by a finite element analysis.