기관회원 [로그인]
소속기관에서 받은 아이디, 비밀번호를 입력해 주세요.
개인회원 [로그인]

비회원 구매시 입력하신 핸드폰번호를 입력해 주세요.
본인 인증 후 구매내역을 확인하실 수 있습니다.

회원가입
서지반출
Preparation of Ultra High Molecular Weight Polyethylene with $MgCl_2/TiCl_4$ Catalysts: Effect of Temperature and Pressure
[STEP1]서지반출 형식 선택
파일형식
@
서지도구
SNS
기타
[STEP2]서지반출 정보 선택
  • 제목
  • URL
돌아가기
확인
취소
  • Preparation of Ultra High Molecular Weight Polyethylene with $MgCl_2/TiCl_4$ Catalysts: Effect of Temperature and Pressure
  • Preparation of Ultra High Molecular Weight Polyethylene with $MgCl_2/TiCl_4$ Catalysts: Effect of Temperature and Pressure
저자명
Shin. Young-Jun,Zhang. He-Xin,Yoon. Keun-Byoung,Lee. Dong-Ho
간행물명
Macromolecular research
권/호정보
2010년|18권 10호|pp.951-955 (5 pages)
발행정보
한국고분자학회
파일정보
정기간행물|ENG|
PDF텍스트
주제분야
기타
이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

The polymerization of ethylene (E) was carried out using a $MgCl_2$-supported $TiCl_4$ catalyst in conjunction with triethylaluminium as a cocatalyst. The effects of the polymerization temperature ($T_p$) and E pressure ($P_E$) on E polymerization were studied. The maximum catalyst activity was obtained at $40^{circ}C$. The melting temperature ($T_m$) and crystallinity ($X_c$) were less affected by the $T_p$. The molecular weight decreased with increasing $T_p$ but the polydispersity index (PDI) increased. In addition, the effect of two stepwise $T_p$ on E polymerization was investigated and the bimodal gel permeation chromatography (GPC) curve was obtained. The catalyst activity increased drastically with increasing $P_E$. The higher $P_E$ in the range of $1-12kgf/cm^2$ showed a higher $M_v$ of the ultra high molecular weight polyethylene (UHMWPE) obtained, whereas increasing $P_E$ decreased the PDI. Because it was very difficult to obtain the molecular weight distribution of UHMWPE through GPC analysis, the molecular weight distribution was analyzed from rheometry measurements of the UHMWPE melt.