In this paper, the electromagnetic (EM) wave absorbers using TiO2 as a dielectric material with chlorinated polyethylene (CPE) were investigated in W-band radio frequencies. We compared the relative permittivity with reflectionless curve and the absorption properties of samples containing 40 wt.%, 50 wt.%, 60 wt.%, 70 wt.%, and 80 wt.% TiO2. It is possible to realize a complex relative permittivity satisfying the reflectionless condition by choosing composition ratio of TiO2. The optimized composition ratio of TiO2 for the maximum absorption property is about 70 wt.%. As a result, we have confirmed the realization of an EM wave absorber with a high absorption property in W-band radio frequencies.