In this paper, we proposed new solution procedure of the air defense missile allocation problem. In order to find the optimal location of missile, we formulated a simple mathematical model maximizing the kill probability of enemy air threat including aircraft and missile. To find the Kill probability, we developed a new procedure using actual experimental data in the mathematical model. Actual experimental data mean real characteristic factor, which was acquired when the missile had been developed through missile fire experiment. The result of this study can offer practical solution for missile allocation and the methodology in this study can be used to the decision making for the optimal military facility allocation.