The Piseo-ri site in Muan provides significant data in investigation on the Paleolithic sites in the southwest coast of Korea. Stratigraphic and geological analysis indicates that the characteristic of soil wedge can vary in accordance with soil property and relief of paleo-surface. Considering that the cultural layer was deposited after the Last Glacial Maximum, co-occurrence of the late Middle to early Upper Paleolithic stone tools suggests a possibility of redeposition of different ages resulted from active erosion. The result shows that the distribution of the Paleolithic tools and the property of soil wedge could be controlled by environmental conditions such as relief of paleo-surface and climate.