This paper presents energy efficiency about an electrolyser which is related with the hybrid system of solar cell and fuel cell for using the system more fully. The water electrolyser is the exact reverse of a hydrogen fuel cell; it produces gaseous hydrogen and oxygen from water. Electrolyser technology may be implemented at a variety of scales wherever there is an electricity supply to provide hydrogen and/or oxygen for virtually any requirement. Also, this paper shows optimum operating point in the electrolyser for saving cost of the electrical energy with hybrid system.