- 환원 석출법을 이용한 모양과 크기가 제어된 금 입자의 제조
- ㆍ 저자명
- 홍소야,이창환,김주용,Hong. So-Ya,Lee. Chang-Hwan,Kim. Joo-Yong
- ㆍ 간행물명
- 韓國染色加工學會誌
- ㆍ 권/호정보
- 2010년|22권 2호|pp.123-131 (9 pages)
- ㆍ 발행정보
- 한국염색가공학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Shape and size controlled synthesis of gold particles has been studied by using wet-chemical method. When ${AuCl_4}^-$ in aqueous $HAuCl_4$ precursor was reduced using $Na_2SO_3$ as a reducing agent, mixtures of spherical, triangular and hexagonal particles were prepared in a few minutes. It was found that the shape selective oxidative etching by ${AuCl_4}^-;+;Cl^-$ anions and crystal growth took place simultaneously. As the ${AuCl_4}^-$ and $Cl^-$ concentration increased, yields of large triangular and hexagonal plate type particles increased, while the spherical particles decreased in most cases. Possible etching and growth mechanisms are discussed.