- Cr-doped Celsian계 녹색안료의 합성과 적용
- ㆍ 저자명
- 정현식,김연주,최수녕,이병하,Chung. Hyun-Sik,Kim. Yeon-Ju,Choi. Soo-Nyong,Lee. Byung-Ha
- ㆍ 간행물명
- 한국세라믹학회지
- ㆍ 권/호정보
- 2010년|47권 5호|pp.450-456 (7 pages)
- ㆍ 발행정보
- 한국세라믹학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
During the process of synthesizing green celsian pigments, attempts were made to replace a given amount of $BaCO_3$ with $SrCO_3$ to accelerate the hexagonal to monoclinic celsian phase transition, which was assumed to promote color development. Monoclinic celsian have been synthesized from Hongkong-Kaolin, $BaCO_3$, $SrCO_3$, $Al(OH)_3$, $SiO_2$ and $SrCO_3$ with 1 to 1.5 wt% of LiF as a mineralizer from 1100 to $1300^{circ}C$. It was found that replacing $BaCO_3$ with $SrCO_3$ allowed monoclinic celsian to be formed at a lower temperature. While the pigments containing 1 mole of $BaCO_3$ were difficult to synthesize monoclinic celsian with absence of the mineralizer, the formation of monoclinic celsian was successfully achieved even without mineralizer by using 0.25 mole of $SrCO_3$ at $1250^{circ}C$ for 1 h. The color development was improved from yellowish green to green with increasing amount of $SrCO_3$ being replaced.