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1,2-Bis(4-trimellitimidophenoxy)benzene으로 부터 유도된 신규 방향족 폴리아미드이미드
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  • 1,2-Bis(4-trimellitimidophenoxy)benzene으로 부터 유도된 신규 방향족 폴리아미드이미드
  • Noble Aromatic Poly(amide-imide)s Derived from 1,2-Bis(4-trimellitimidophenoxy)benzene
저자명
정화진,Jeong. Hwa-Jin
간행물명
한국유화학회지
권/호정보
2010년|27권 2호|pp.129-136 (8 pages)
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한국유화학회
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정기간행물|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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A series of noble poly(amide-imide)s and copoly(amide-imide)s bearing 1,2-bis(4-phenoxy)benzene units were synthesized by the direct polycondensation of 1,2-bis(4-trimellitimidophenoxy)benzene[1,2-PTPB] with a combination of commercially available aromatic diamines and diacids such as m-phenylene diamine, p-phenylene diamine(PPD), isophthalic acid and terephthalic acid(TA) in N-methyl-2-pyrrolidone(NMP) using triphenyl phosphite and pyridine as a condensing agent in the presence of dehydrating agent ($CaCl_2$). The resulting polymers had inherent viscosities in the range of 0.37~0.78 dL/g and most of them were soluble m common organic solvents including NMP, dimethylacetamide, dimethylsulfoxide, dimethylformamide, and m-cresol. Wide-angle X-ray diffractograms revealed that the copoly(amide-imide) derived from PPD with mixed acids of 1,2-BTPB and TA, showed crystalline nature, whereas all of the other polymers were found to be amorphous. The glass transition temperatures of the polymers occurred over the temperature range of $270{sim}323^{circ}C$ in their differential scanning calorimetry curves and their 10% weight loss temperature, determined by thermogravimetric analysis in air and nitrogen atmosphere, were in the range $465{sim}535^{circ}C$, $500{sim}550^{circ}C$, respectively, indicating their good thermal stability.