$[t-BuNSiMe_2(3,6-t-Bu_2Flu)]TiMe_2$ (1) combined with trialkylaluminum-free modified methylaluminoxane (dMMAO) was used to induce the living polymerization of propylene in toluene at -20, 0, and $25^{circ}C$ with control of the syndiospecificity. After the first polymerization at $-20^{circ}C$, the same amounts of propylene were added at $25^{circ}C$ for the second polymerization. The resulting PP was syndiotactic-rich (rr = 0.75), the value of which is the arithmetical average ((0.89 + 0.60)/2 = 0.745) of those produced at -20 and $25^{circ}C$. These results indicate the formation of the expected syndiotactic-atactic di-stereoblock PP.