Let G be a compact and connected semisimple Lie group, H a closed subgroup, g (resp. h) the Lie algebra of G (resp. H), B the Killing form of g, g the normal metric on the homogeneous space G/H which is induced by -B. Let D be an invarint connection with Weyl structure (D, g, ${omega}$) in the tangent bundle over the normal homogeneous Riemannian manifold (G/H, g) which is projectively flat. Then, the affine connection D on (G/H, g) is a Yang-Mills connection if and only if D is the Levi-Civita connection on (G/H, g).