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Analysis of the Wettability of Partially Fluorinated Polymers Reveals the Surprisingly Strong Acid-Base Character of Poly(vinylidene Fluoride)
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  • Analysis of the Wettability of Partially Fluorinated Polymers Reveals the Surprisingly Strong Acid-Base Character of Poly(vinylidene Fluoride)
저자명
Lee. Sang-Wha,Park. Joon-Seo,Lee. T. Randall
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2011년|32권 1호|pp.41-48 (8 pages)
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The wettabilities of the partially fluorinated polymers (ethylene-tetrafluoroethylene copolymer (ETFE), ethylenechlorotrifluoroethylene copolymer (ECTFE), and poly(vinylidene fluoride) (PVDF)) were investigated by contact angle measurements. Zisman plots for ETFE and ECTFE exhibited linear relationships, while the Zisman plot for PVDF showed a slight curvature, which was interpreted to indicate strong non-dispersive interactions between the surface and the contacting liquids. The Lifshitz-van der Waals forces of the fluoropolymers were estimated to increase in the order of ETFE < PVDF $ll$ ECTFE. An evaluation of the polar or "acid-base" interaction energies showed that PVDF, which possesses the most acidic hydrogens among the examined fluoropolymers, has the strongest acid-base interactions.