- 액상 에폭시 수지와 마이크로/나노 하이브리드 실리카 혼합물의 점도 예측
- ㆍ 저자명
- 황광춘,이충희,이종근,Huang. Guang-Chun,Lee. Chung-Hee,Lee. Jong-Keun
- ㆍ 간행물명
- 한국재료학회지
- ㆍ 권/호정보
- 2011년|21권 2호|pp.100-105 (6 pages)
- ㆍ 발행정보
- 한국재료학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
The relative viscosity was measured at different filler loadings for a cycloaliphatic epoxy resin and hexahydro-4-methylphthalic anhydride hardener system filled with micro/nano hybrid silica. Various empirical models were fitted to the experimental data and a fitting parameter such as critical filler fractions (${phi}_{max}$) was estimated. Among the models, the Zhang-Evans model gave the best fit to the viscosity data. For all the silica loadings used, ln (relative viscosity) varied linearly with filler loadings. Using the Zhang-Evans model and the linearity characteristics of the viscosity change, simple methods to predict the relative viscosity below ${phi}_{max}$ are presented in this work. The predicted viscosity values from the two methods at hybrid silica fractions of $phi$ = 0.086 and 0.1506 were confirmed for a micro:nano = 1:1 hybrid filler. As a result, the difference between measured and predicted values was less than 11%, indicating that the proposed predicting methods are in good agreement with the experiment.