The aim of this study was to analysis the Heating/cooling performance and Daylighting performance of Solar Window System built in apartments. the solar window is the idea to integrate daylight as a third form of solar energy into a PV/Solar Collector system. The process of this study is as follows: 1)Solar Window system was designed through the investigation of previous paper and work. 2)The simulation program(Lightscape3.2) was used in daylighting performance analysis. the reference model of simulation was made up to analysis daylighting performance on Solar Window system. 3)The simulation program(ESP-r, Therm5.0, Window6.0) was used in energy performance analysis. the reference model of simulation was made up to analysis energy and daylighting performance on Solar Window system. 4)The Size of Simulation model for daylighting and heating/cooling energy analysis was $148.5m^2$ 5)The lighting performance analysis was carried out with various variants, such as the size and installed area of Solar Window system. 6)Energy performance simulation was carried out with various variants, such as Integrated U-value of Solar Window system according to its position, installed angle and insulation thickness. Consequently, When Solar Window system is equipped with balcony window of Apartment, Annual heating and cooling energy of reference model was cut down at the average of $4.1kWh/m^2$ or 4.2%.