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서지반출
Elucidation of Electrode Reaction of EuCl3 in LiCl-KCl Eutectic Melts through CV Curve Analysis
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  • Elucidation of Electrode Reaction of EuCl3 in LiCl-KCl Eutectic Melts through CV Curve Analysis
  • Elucidation of Electrode Reaction of EuCl3 in LiCl-KCl Eutectic Melts through CV Curve Analysis
저자명
Kim. Tack-Jin,Jung. Yong-Ju,Kim. Si-Hyung,Paek. Seung-Woo,Ahn. Do-Hee
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2011년|32권 3호|pp.863-866 (4 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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기타
이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

The electrode reaction of $Eu^{3+}$ in a LiCl-KCl eutectic melt has been re-examined using cyclic voltammetry (CV). In this work, for the first time, the kinetic details of a $Eu^{3+}/Eu^{2+}$ redox system have been completely elucidated, along with the thermodynamic property, through a curve fitting applied to experimental CV data, which were obtained in a wide scan rate range of 0.5 to 10 V/s. The simulated results showed an excellent fit to all experimental CV data simultaneously, even though the curve fittings were performed within a large dynamic range of initial transfer coefficient values, formal potentials, and standard rate constants. As a result, a proper formal potential, transfer coefficient, and standard rate constant for the $Eu^{3+}/Eu^{2+}$ redox system were successfully extracted using the CV curve fitting.