Compressed natural gas (CNG) is well known as one of the cleanest burning alternative fuels. Bi-fuel CNG vehicle can also run on gasoline or another fuel while dedicated natural gas vehicle is designed to run on natural gas only. Recently, increased attention has been focused on bi-fuel CNG/LPG taxi because of good fuel economy of CNG. A number of LPG taxis modified to CNG Bi-fuel vehicles are running in many cities. In this paper, the emissions characteristics of in-use passenger cars running on CNG and LPG were investigated. Chassis dynamometer test was used to measure exhaust emissions from an in-use fleet of 5 cars. Exhaust emissions were collected for CVS-75 driving mode. The test results showed that for CNG fuel mode, CO, $CO_2$ and NMHC emissions decreased to 9%, 12% and 14% respectively, and $CH_4$ and $NO_x$ emissions increased to 317% and 47% respectively.