This paper contains of descriptions of deterioration diagnosis of the surface and a coating layer for maintenance managements of large spatial structures with membrane structure. Membrane is a roofing material of the structures that its performance of durability including its performance of chemical resistance and corrosive resistance is considered to be highly important. In general, the items of diagnosis for maintenance managements such as membrane extensively include the diagnosis of deterioration of the membrane surface, of a coating layer of membrane, the diagnosis of deterioration between a coating layer and fiber, of overall surface of membrane, of the class of ropes, of reinforced belts, and of the cover of rubber. The object of this study that needs maintenance managements of the membrane with PVC and FIFE which are commonly used and shows the diagnosis results of deterioration of the surface and a coating layer.