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Structural and Magnetic Properties of Dilute Spinel Ferrites: Neutron Diffractometry and Magnetometry Investigations
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  • Structural and Magnetic Properties of Dilute Spinel Ferrites: Neutron Diffractometry and Magnetometry Investigations
  • Structural and Magnetic Properties of Dilute Spinel Ferrites: Neutron Diffractometry and Magnetometry Investigations
저자명
Mamiya. H.,Terada. N.,Kitazawa. H.,Hoshikawa. A.,Ishigaki. T.
간행물명
Journal of magnetics
권/호정보
2011년|16권 2호|pp.134-139 (6 pages)
발행정보
한국자기학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Magnetic properties of highly zinc-substituted manganese ferrites are discussed on the basis of cation distribution. High throughput neutron powder diffractometry indicates that the prepared samples possess a nearly normal spinel structure, where the substitution of nonmagnetic zinc ions mainly causes the dilution of magnetic ions in the A-sublattice and consequently affects bond-randomness in the B-sublattice. On the other hand, the estimated occupancy of manganese ions in the B site indicates that random anisotropy effects due to local Jahn-Teller distortions gradually weaken with the substitution. Bulk magnetometry indicates that the substitution smears the transition from a paramagnetic phase to a soft-magnetic phase. Furthermore, at lower temperatures, such a soft-magnetic phase is destabilized and a magnetic glassy state appears. These features of the magnetic properties of dilute spinel ferrites are discussed from the viewpoint of the above-mentioned various types of disorders.