This article employs Least Square Support Vector Machine (LSSVM) for determination of fracture parameters of concrete: critical stress intensity factor ($K_{Ic}^s$) and the critical crack tip opening displacement ($CTOD_c$). LSSVM that is firmly based on the theory of statistical learning theory uses regression technique. The results are compared with a widely used Artificial Neural Network (ANN) Models of LSSVM have been developed for prediction of $K_{Ic}^s$ and $CTOD_c$, and then a sensitivity analysis has been performed to investigate the importance of the input parameters. Equations have been also developed for determination of $K_{Ic}^s$ and $CTOD_c$. The developed LSSVM also gives error bar. The results show that the developed model of LSSVM is very predictable in order to determine fracture parameters of concrete.