- 액상환원공정을 이용한 나노 코발트 분말의 합성
- ㆍ 저자명
- 홍현선,고영대,강이승,김건홍,정항철,Hong. Hyun-Seon,Ko. Young-Dae,Kang. Lee-Seung,Kim. Geon-Hong,Jung. Hang-Chul
- ㆍ 간행물명
- 한국분말야금학회지
- ㆍ 권/호정보
- 2011년|18권 3호|pp.244-249 (6 pages)
- ㆍ 발행정보
- 한국분말야금학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Spherical nanosized cobalt powder with an average size of 150-400 nm was successfully prepared at room temperature from cobalt sulfate heptahydrate ($CoSO_4{cdot}7H_2O$). Wet chemical reduction method was adopted to synthesize nano cobalt powder and hypophosphorous acid ($H_3PO_2$) was used as reduction agent. Both the HCP and the FCC Co phase were developed while $CoSO_4{cdot}7H_2O$ concentration ranged from 0.7 M to 1.1 M. Secondary phase such as $Co(OH)_2$ and $CO_3O_4$ were also observed. Peaks for the crystalline Co phase having HCP and FCC structure crystallized as increasing the concentration of $H_3PO_2$, indicating that the amount of reduction agent was enough to reduce $Co(OH)_2$. Consequently, a homogeneous Co phase could be developed without second phase when the $H_3PO_2/CoSO_4{cdot}7H_2O$ ratio exceeded 7.