For decreasing of the casualties and designing of the smoke control systems in the ultra high-rise building, the programs for analysis of smoke control were developed for prediction of smoke spread and distributions of pressure and temperature in building fire situation. In this study, coupling algorithm between mass and enthalpy conservations was modified for improving the applicability of the CAU_ESCAP which program can consider the energy transfer. The fire situation in ultra high-rise building was applied by using the modified CAU_ESCAP. Results of pressure difference predicted by modified CAU_ESCAP are higher than results of ASCOS as stack effect is generated due to the increasing of stairway temperature. Moreover, theoretically, the result of the neutral plane is more accurate than the result of ASCOS, in fire situation of ultra high-rise building.