Aluminum or CFRP is representative one of the lightweight materials. Collapse behavior of Al/CFRP square structural member was evaluated in this study based on the respective collapse behavior of aluminum and CFRP member. Al/CFRP square structural members were manufactured by wrapping CFRP prepreg sheets outside the aluminum hollow members in the autoclave. Because the CFRP is an anisotropic material with mechanical properties, The Al/CFRP square structural members stacked at different angles(${pm}15^{circ}$, ${pm}45^{circ}$, ${pm}90^{circ}$, $90^{circ}/0^{circ}$ and $0^{circ}/90^{circ}$ where the direction on $0^{circ}$ coincides with the axis of the member) and interface numbers(2, 3, 4, 6 and 7). The axial impact collapse tests were carried out for each section members. Collapse mode and energy absorption characteristics of the each member were analyzed.