Currently, office buildings in Korea tend to adopt as their outer wall the curtain wall structure which can be easily constructed and has beautiful external appearance as well. However, the problem is that the curtain wall structure does not have a uniform composition unlike the wall of existing reinforced concrete structures and has a frame made of metal with high heat conduction. Therefore, it is expected that the structure will be highly influenced by the thermal bridge. Thereupon, this study analyzes how to set up the composition of the wall system and heat transmission rate in consideration of the thermal characteristics of the curtain wall structure and applies it in practice by simulation in order to propose a guideline for the energy simulation method of the curtain wall structure and analyze its differences from existing simulation methods.