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산화물 환원공정에 의해 제조된 Bi2Te2.7Se0.3 분말의 열전특성
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  • 산화물 환원공정에 의해 제조된 Bi2Te2.7Se0.3 분말의 열전특성
저자명
박배건,이길근,김우열,하국현,Park. Bae-Gun,Lee. Gil-Geun,Kim. Woo-Yeol,Ha. Gook-Hyun
간행물명
한국분말야금학회지
권/호정보
2011년|18권 5호|pp.437-442 (6 pages)
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한국분말야금학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The present study focused on the synthesis of Bi-Te-Se-based powder by an oxide-reduction process, and analysis of the thermoelectric properties of the synthesized powder. The phase structure, chemical composition, and morphology of the synthesized powder were analyzed by XRD, EPMA and SEM. The synthesized powder was sintered by spark plasma sintering. The thermoelectric properties of the sintered body were evaluated by measuring its Seebeck coefficient, electrical resistivity, and thermal conductivity. $Bi_2Te_{2.7}Se_{0.3}$ powder was synthesized from a mixture of $Bi_2O_3$, $TeO_2$, and $SeO_2$ powders by mechanical milling, calcination, and reduction. The sintered body of the synthesized powder exhibited n-type thermoelectric characteristics. The thermoelectric properties of the sintered bodies depend on the reduction temperature. The Seebeck coefficient and electrical resistivity of the sintered body were increased with increasing reduction temperature. The sintered body of the $Bi_2Te_{2.7}Se_{0.3}$ powder synthesized at $360^{circ}C$ showed about 0.5 of the figure of merit (ZT) at room temperature.