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Photoluminescence of CuInS2/(Cd,Zn)S Nanocrystals as a Function of Shell Composition
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  • Photoluminescence of CuInS2/(Cd,Zn)S Nanocrystals as a Function of Shell Composition
  • Photoluminescence of CuInS2/(Cd,Zn)S Nanocrystals as a Function of Shell Composition
저자명
Kim. Young-Kuk,Ahn. Si-Hyun,Choi. Gyu-Chae,Chung. Kook-Chae,Cho. Young-Sang,Choi. Chul-Jin
간행물명
Transactions on electrical and electronic materials
권/호정보
2011년|12권 5호|pp.218-221 (4 pages)
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한국전기전자재료학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

We modified the optical properties of the $CuInS_2$ nanocrystal (NC) by alloying. Nanocrystals (NCs) with alloyed cores were synthesized by refluxing the as-synthesized $CuInS_2$ NCs with a mixture of cadmium acetate, zinc acetate and palmitic acid. The shift in emission wavelength of the NCs after shell layer formation was minimized by alloying. The photoluminescence (PL) spectra showed significant reduction of emission intensity. A detailed study on the emission process of NCs implies that the formation of shell layers with small lattice mismatch minimized the mismatch strain generated from the shell layers in contrast to core alloyed NCs. In particular, time-resolved PL spectra of the NCs showed a significant increase in the lifetime of excited carriers by modifying the band alignment of the NCs by modifying the shell composition.