Considerations for green house gas (GHG) monitoring over next generation network (NGN) are regarded as a green convergence service for the successful reduction of GHG emission leading to resolve global warming issue in that NGN is expected to provide secure connections to fixed-and-mobile converged (FMC) features. Model-based scenario approach is an appropriate way to standardize and actualize the desired service. This paper first describes the service scenario of GHG monitoring service over NGN.