Due to the effect of surface tension, liquid film around a curved edge of solid surface moves from the corner to the flat surface. During this behavior of liquid film, film sagging phenomenon is easily occurred at the solid surface. Behavior of liquid film is determined with the effects of the properties of liquid film and the geometric factors of solid surface. In the present study, 2-D transient CFD simulations were conducted on the behavior of liquid film around a curved edge. The two-phase interfacial flow of liquid film was numerically investigated by using a VOF method in order to predict the film sagging around a curved edge. In the steady state of behavior of liquid film, the liquid film thickness of numerical result showed a good agreement with experimental data. After verifying the numerical results, the characteristics of behavior of liquid film were numerically analyzed with various properties of liquid film such as surface tension coefficient and viscosity. The effects of geometric factors on film sagging were also investigated to reduce the film sagging around a curved edge.