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MoO3/camphene 슬러리의 동결건조 및 수소환원에 의한 Mo 다공체 제조
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  • MoO3/camphene 슬러리의 동결건조 및 수소환원에 의한 Mo 다공체 제조
저자명
이원석,오승탁,Lee. Wonsuk,Oh. Sung-Tag
간행물명
한국분말야금학회지
권/호정보
2012년|19권 6호|pp.446-450 (5 pages)
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한국분말야금학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

In order to fabricate the porous Mo with controlled pore characteristics, unique processing by using $MoO_3$ powder as the source and camphene as the sublimable material is introduced. Camphene-based 15 vol% $MoO_3$ slurries, prepared by milling at $50^{circ}C$ with a small amount of dispersant, were frozen at $-25^{circ}C$. Pores were generated subsequently by sublimation of the camphene during drying in air for 48 h. The green body was hydrogen-reduced at $750^{circ}C$, and sintered at $1000-1100^{circ}C$ for 1 h. After heat treatment in hydrogen atmosphere, $MoO_3$ powders were completely converted to metallic W without any reaction phases. The sintered samples showed large pores with the size of about $150{mu}m$ which were aligned parallel to the camphene growth direction. Also, the internal wall of large pores and near bottom part of specimen had relatively small pores due to the difference in the camphene growth rate during freezing process. The size of small pores was decreased with increase in sintering temperature, while that of large pores was unchanged. The results are strongly suggested that the porous metal with required pore characteristics can be successfully fabricated by freeze-drying process using metal oxide powders.