With rapid modernization and industrialization, many urban areas are becoming overcrowded at a rapid pace and such urban ecological problems as heat island effect are becoming serious due to the reduced green zones resulted from the indiscriminate development. To solve this problem, ecological park, constructed wetlands, and greening on the elevation, balcony, and roof of a building that have the structure and function very close to the state of nature are currently being promoted at the urban or regional level. Especially green roof will be able to not only provide the center of a city with a significant portion of green area but also help to relive heat island effect and improve micro climate by preventing concrete of a building from absorbing heat. According to a recent study, the temperature of green roof in the summer season shows a lower temperature than the outdoor temperature, but inversely the concrete surface shows a higher temperature. Accordingly, this study measured the surface temperature of buildings with green roof in Daejeon area in order to determine how the green roof system would have an impact on the distribution of surface temperature and did a comparative analysis of the distribution of the surface temperature of green roof vs non-green roof based on these theoretical considerations. As a result, it was found that the surface temperature of green roof was lower by $4{sim}7^{circ}C$ than that of non-green roof. This is expected to contribute to the mitigation of urban heat island effects.