- 저급 석탄과 혼합한 폐촉매의 수증기 가스화 반응에 미치는 영향
- ㆍ 저자명
- 곽재훈,서석진,이소정,송병호,손정민,Kwak. Jaehoon,Seo. Seokjin,Lee. Sojung,Song. Bungho,Sohn. Jung Min
- ㆍ 간행물명
- 한국수소 및 신에너지학회 논문집
- ㆍ 권/호정보
- 2012년|23권 6호|pp.647-653 (7 pages)
- ㆍ 발행정보
- 한국수소및신에너지학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
We have investigated the kinetics and activity of waste catalysts for steam-lignite gasification. Waste catalysts I, II, III and reference $K_2CO_3$ were used and physical mixed with a coal. The gasification experiments were carried out with the low rank coal loaded with 1 wt% and 5 wt% catalyst at the temperature range from 700 to $900^{circ}C$ using thermobalance reactor. It was observed that the carbon conversion reached almost 100% regardless of the kinds of catalysts at $900^{circ}C$. The shortest time to reach the designated conversion was obtained for 1 wt% waste catalyst II and 5 wt% $K_2CO_3$ at $900^{circ}C$. The gasification reaction rate constant increased with increasing the temperature. Highest rate constant was obtained with $K_2CO_3$ at $900^{circ}C$. The lowest activation energy was 69.42 kJ/mol for 5 wt% waste catalyst II. The waste catalyst had an influence on the reduction of activation energy.