Spectro-polarimetry is the most powerful technique for deducing the magnetic structure of the Sun. Stokes vector allow us to infer the physical conditions in the solar atmosphere prevailing during the line formation. Inversion codes are the main tool to extract this information from the Stokes spectra. This study will focus on measurements of the chromospheric He I 1083.0 nm triplet and the photospheric Si I 1082.7 nm line. A spectropolarimetric data set of sunspots, obtained with the German Vacuum Tower Telescope (VTT) at the Teide observatory on Tenerife, is analyzed using an inversion technique. We will introduce the German Vacuum Tower Telescope and the inversion code HeLix, and will show data sets that are analyzed by HeLix. Finally I made variety plots and maps for understanding photospheric and chromospheric layers of sunspots.