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Spark Plasma Sintering으로 제조한 Li2O-2SiO2 유리 소결체의 전기적 특성
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  • Spark Plasma Sintering으로 제조한 Li2O-2SiO2 유리 소결체의 전기적 특성
저자명
윤혜원,송철호,양용석,윤수종,Yoon. Hae-Won,Song. Chul-Ho,Yang. Yong-Seok,Yoon. Su-Jong
간행물명
한국재료학회지
권/호정보
2012년|22권 2호|pp.61-65 (5 pages)
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한국재료학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

A $Li_2O-2SiO_2$ ($LS_2$) glass was investigated as a lithium-ion conducting oxide glass, which is applicable to a fast ionic conductor even at low temperature due to its high mechanical strength and chemical stability. The $Li_2O-2SiO_2$ glass is likely to be broken into small pieces when quenched; thus, it is difficult to fabricate a specifically sized sample. The production of properly sized glass samples is necessary for device applications. In this study, we applied spark plasma sintering (SPS) to fabricate $LS_2$ glass samples which have a particular size as well as high transparency. The sintered samples, $15mmphi{ imes}2mmT$ in size, ($LS_2$-s) were produced by SPS between $480^{circ}C$ and $500^{circ}C$ at 45MPa for 3~5mim, after which the thermal and dielectric properties of the $LS_2$-s samples were compared with those of quenched glass ($LS_2$-q) samples. Thermal behavior, crystalline structure, and electrical conductivity of both samples were analyzed by differential scanning calorimetry (DSC), X-ray diffraction (XRD) and an impedance/gain-phase analyzer, respectively. The results showed that the $LS_2$-s had an amorphous structure, like the $LS_2$-q sample, and that both samples took on the lithium disilicate structure after the heat treatment at $800^{circ}C$. We observed similar dielectric peaks in both of the samples between room temperature and $700^{circ}C$. The DC activation energies of the $LS_2$-q and $LS_2$-s samples were $0.48{pm}0.05eV$ and $0.66{pm}0.04eV$, while the AC activation energies were $0.48{pm}0.05eV$ and $0.68{pm}0.04eV$, respectively.