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Adsorption, Mobility and Degradation of Diphenamid in Chinese Soils
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  • Adsorption, Mobility and Degradation of Diphenamid in Chinese Soils
  • Adsorption, Mobility and Degradation of Diphenamid in Chinese Soils
저자명
Wu. Xiaomao,Li. Ming,Long. Youhua,Liu. Renxiang,Yu. Yunlong,Fang. Hua
간행물명
KSCE journal of civil engineering
권/호정보
2012년|16권 4호|pp.547-553 (7 pages)
발행정보
대한토목학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The present study was conducted to determine adsorption, mobility, and degradation characteristics of diphenamid in five Chinese soils and their relationships. The adsorption of diphenamid in soils tested could accurately be described by a Freundlich equation. Based on the mobility factor ($R_f$), diphenamid was seen to be slightly or moderately mobile in soils studied. Regression of $K_f$ and $R_f$ against selected soil properties indicated that Organic Matter (OM) was the most influential factor governing adsorption and mobility of diphenamid ($r^2$ > 0.92 ) followed by clay ($r^2$ > 0.61). There was a significant correlation (p < 0.01) between $K_f$ and $R_f$ of diphenamid. Diphenamid degradation data were fitted the first-order reaction equations, yielding half-lives ($T_{1/2}$) ranging from 187.3 to 247.5 days in unsterilized soils but prolonging to 577.5-630.0 days in sterilized soils. The prolonged $T_{1/2}$ by sterilization showed that microbial degradation was the dominant pathway for diphenamid degradation in soils. Degradation of diphenamid in soils appeared to be influenced by soil OM ($r^2$ > 0.97) and clay content ($r^2$ > 0.85). The $T_{1/2}$ of diphenamid was significantly related to both $K_f$ and $R_f$ (p < 0.05), indicating that either $K_f$ or $R_f$ might be used as a model for predicting degradation of diphenamid in soils involved.