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Facile Fabrication of Superhydrophobic Cotton Fabric from Stearyl Methacrylate Modified Polysiloxane/Silica Nanocomposite
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  • Facile Fabrication of Superhydrophobic Cotton Fabric from Stearyl Methacrylate Modified Polysiloxane/Silica Nanocomposite
  • Facile Fabrication of Superhydrophobic Cotton Fabric from Stearyl Methacrylate Modified Polysiloxane/Silica Nanocomposite
저자명
Hao. Lifen,An. Qiufeng,Xu. Wei
간행물명
Fibers and polymers
권/호정보
2012년|13권 9호|pp.1145-1153 (9 pages)
발행정보
한국섬유공학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The stearyl methacrylate modified polysiloxane/nanocomposite was synthesized by graft copolymerization between stearyl methacrylate modified polysiloxane with pendent epoxy groups and amino-functionalized nano silica. Then it was utilized to fabricate the superhydrophobic cotton fabric by one-step method. The structures, chemical compositions, thermal properties, surface morphology and wettability were characterized by Fourier Transform Infrared Spectrum (FT-IR), X-ray photoelectron spectroscopy (XPS), Thermo-gravimetric analyzer (TGA), Scanning electron microscopy (SEM) and Static contact angle analyzer. Results showed that a hydrophobic polysiloxane film and many nano-scaled tubercles were coated on the surface of the treated cotton fabrics plus their inherent microscaled roughness, which were the reasons why cotton fabric changed from hydrophilicity to hydrophobicity. In addition, with increase of the amount of nanocomposite, hydrophobicity of the treated cotton fabric would be enhanced; water contact angle of this fabric could attain $157^{circ}$, which was higher than $141.5^{circ}$ reached by the fabric treated with stearyl methacrylate modified polysiloxane. The superhydrophobic cotton fabric also possessed favorable washing durability. On the other hand, its air permeability, color and softness would not be influenced instead.