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Excess Volumes, Speeds of Sound, Isentropic Compressibilities and Viscosities of Binary Mixtures of N-Ethyl Aniline with Some Aromatic Ketones at 303.15 K
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  • Excess Volumes, Speeds of Sound, Isentropic Compressibilities and Viscosities of Binary Mixtures of N-Ethyl Aniline with Some Aromatic Ketones at 303.15 K
  • Excess Volumes, Speeds of Sound, Isentropic Compressibilities and Viscosities of Binary Mixtures of N-Ethyl Aniline with Some Aromatic Ketones at 303.15 K
저자명
Gowrisankar. M.,Sivarambabu. S.,Venkateswarlu. P.,Kumar. K. Siva
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2012년|33권 5호|pp.1686-1692 (7 pages)
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대한화학회
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정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

Densities (${ ho}$), Viscosities (${eta}$) and ultrasonic speeds (u) of pure acetophenone (AP), propiophenone (PP), $p$-methyl acetophenone ($p$-MeAP), $p$-chloroacetophenone ($p$-ClAP) and those of their binary mixtures with $N$-ethyl aniline ($N$-EA) as a common component, were measured at 303.15 K over the entire composition range. These experimental data were used to calculate the excess volume $V^E$, deviation in ultrasonic speeds ${Delta}u$, isentropic compressibility $K_s$, intermolecular free length $L_f$, acoustic impedance Z, deviations in isentropic compressibility ${Delta}K_s$, deviation in viscosity ${Delta}{eta}$ and excess Gibbs free energy of activation of viscous flow ($G^{*E}$) at all mole fractions of $N$-ethyl aniline. These parameters, especially excess functions, are found to be quite sensitive towards the intermolecular interactions between component molecules. Theoretical values of viscosity of the binary mixtures were calculated using different empirical relations and theories. The relative merits of these relations and theories were discussed. The experimental results were correlated by using the polynomial proposed by Redlich-Kister equation.