- (1-x)Pb(Yb1/2Nb1/2)O3-xPbTiO3 (0.40 ≤ x ≤ 0.60) 고용계에서의 PbTiO3 치환에 따른 상전이 영역의 상전이 거동과 유전특성
- ㆍ 저자명
- 김정현,Kim. Jung-Hyun
- ㆍ 간행물명
- 한국세라믹학회지
- ㆍ 권/호정보
- 2012년|49권 3호|pp.253-259 (7 pages)
- ㆍ 발행정보
- 한국세라믹학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
In this study, crystal structural changes and dielectric properties of $(1-x)Pb(Yb_{1/2}Nb_{1/2})O_3-xPbTiO_3$ ((1-x)PYN-xPT) solid solutions were measured and analyzed with respect to the $PbTiO_3$ (PT) contents ($0.40{leq}x{leq}0.60$). From X-ray diffraction (XRD) measurements, (1-x)PYN-xPT solid solutions showed changes of the crystal structure from pseudocubic ($0.40{leq}x{leq}0.44$) to tetragonal ($0.52{leq}x{leq}0.60$) on increasing PT contents and exhibited the coexistence of pseudocubic and tetragonal phase near the morphotropic phase boundary (MPB) composition ($0.46{leq}x{leq}0.50$). The dielectric constant showed a maximum value at x = 0.46 and the maximum values in (1-x)PYN-xPT decreased with higher PT contents. The phase transition temperatures of (1-x)PYN-xPT solid solutions increased over the whole composition ranges tested ($0.40{leq}x{leq}0.60$).