The pros and cons of green building thermal insulation materials and systems have been reviewed from traditional thermal insulation materials such as mineral wool and polyurethane to new thermal insulation materials like VIP and aerogel and future insulating VIM and DIM. VIPs and aerogels with very low thermal conductivity can use for green buildings to significantly increase residential area by reducing energy consumption. Aerogels can be produced as not only opaque and but also translucent forms, thus enabling a wide range of possible building application. For building applications, there are many properties to consider like building site adaptability and mechanical strength, fire protection, cost and environmental impact.